Refractory Applications Of Magnesium Aluminate Spinelrefractory Applications Of Magnesium Aluminate Spinel
Studies on densification mechanical micro structural and
The present work intends to study the development of magnesium aluminate spinel aggregates from Indian magnesite in a single firing stage The raw magnesite has been evaluated in terms of chemical analysis differential thermal analysis thermogravimetric analysis infrared spectroscopy and X ray diffraction
Get PriceCompressive creep of magnesium aluminate spinel
Creep is a major mechanism of failure for many refractory materials Refractories synthesized from raw materials contain vitreous secondary phases which cause creep problems A creep test was utilized to test specimens in order to understand the mechanisms which take place at high temperature through determination of the creep rates activation energies and stress exponents of the specimens
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1 Introduction Magnesium aluminate MgAl 2 O 4 spinel containing castables abbreviated as MA spinel are widely used as steel ladle linings due to their good thermo mechanical properties thermal shock resistance and high corrosion resistance to acidic and basic slags terms of a high corrosion resistance as well as low infiltration depth the optimal spinel content is found in the
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What is claimed is 1 A process for the production of high purity magnesium aluminate spinel refractory which comprises blending alumina in the form of ESP fines with a finely divided source of magnesia in such proportion as to provide a magnesia alumina weight ratio of about 0 4 to 0 8 and heating said blend to a temperature of from about 1600° to 2100°C for a period of time sufficient for
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Aiming at optimizing properties of alumina spinel refractory castables coarse corundum particles were replaced partially with the particles of a novel porous multi component CMA CaO MgO Al2O3 aggregate in the same size Properties including the bulk density apparent porosity strength slag corrosion resistance thermal shock resistance and thermal fatigue resistance of alumina spinel
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Reaction sintering of magnesia rich magnesium aluminate spinel MgO 34 wt was done in the temperature range of 1600–1700 °C Reactivity of constituent alumina was varied by changing the calcination temperature up to 1600 °C
Get PriceMagnesium Alumina Spinel BrickRefractory Materials in
Magnesium alumina spinel is a member of a group of oxides that have the same crystal structure which is named the spinel structure Magnesium aluminate spinel is synthesized and then added to magnesia refractory brick compositions in the range of 0–30 weight percentages
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chiometric spinel of 2135 °C All spinels have the ability to substitute large percentages of one or both of the cationic site components Al3 or Mg2 with other elements with the same charge and similar atom size These specific interac tions with corrosive media especially steel slag explain the use of magnesium aluminate spinels in
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Magnesium aluminate spinel MgAl 2 O 4 is an excellent refractory oxide of immense technological importance as a structural ceramic It possesses useful physical chemical and thermal properties both at normal and elevated temperatures Spinel can be used in formation of refractory bricks in combination with magnesia in two ways
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Applications of Magnesium Aluminate Homogenous Spinel Material Magnesium Aluminate matrix material allows creation of optically transparent high strength ceramics as it allows transmission of light without any loss This transparent ceramic also acts as an armour allowing its
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The chemistry and distribution of phases formed in a set of six laboratory prepared magnesia magnesium aluminate spinel ceramics and in three of their precursor spinel based compositions sintered at 1600°C and 1760°C respectively are examined and compared The evaluation of the results is the basis for the industry design of magnesia spinel refractories for new advanced applications
Get PriceA review on magnesium aluminate MgAl2O4 spinel
Magnesium aluminate MgAl2O4 spinel MAS is a synthetic material with cubic crystal structure and excellent chemical thermal dielectric mechanical and optical properties These properties made MAS an indispensable material for optically transparent windows domes and armours and for certain refractory applications
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Magnesium aluminate spinel containing refractories are widely used as steel ladle linings and represent potential materials for other high temperature processes In gasifiers the refractories are in contact with calcium aluminosilicate rich slags with high content of iron and sulphur
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Nanopowders of magnesium aluminate MgAl 2 O 4 spinel prepared through citrate nitrate gel method and calcined at 800°C were incorporated to the matrix of magnesia carbon MgO C refractory The physical and chemical properties of the nano MgAl 2 O 4 spinel added 0 5 and 1 0 wt MgO C bricks were compared with those of MgO C bricks containing no spinel and commercially
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IMPORTANCE OF MAGNESIUM ALUMINATE SPINEL Mag Al spinel is used for refractory as well as structural applications at elevated temperatures due to its high melting point excellent mechanical strength and impressive chemical resistance It is the most Stable compound present in the MgO Al
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Magnesium aluminate spinel is a material of enormous importance for several industrial applications owing to synergy of various advantageous properties like high melting point 2135 °C good mechanical strength superior thermal shock resistance as well as excellent resistance to corrosion low thermal expansion and low di electric constant
Get PriceFused Spinel Alumina Magnesia Spinel Spinel Refractory
Alumina Magnesia Spinel Fused Spinel Alumina Magnesia Spinel is one of the most resistant refractory compounds It has great features such as low thermal working temperature outstanding refractoriness thermal stability and chemical stability Fused Spinel Alumina Magnesia Spinel is a highly recommended refractory raw material
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Magnesium aluminate spinel MgAl2O4 the only compound forms in the MgO Al2O3 system has the most desirable characteristics for refractory application along with the environmental friendliness Other than refractory there are studies for its applications as humidity sensors transparent ceramic anode material in aluminum cell etc
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for refractory applications for example in the steel in dustry because of its suitable high temperature proper ties such as high strength at elevated temperatures and high resistance to basic slags 1 2 Besides the stoichiomet riccomposition 71 8wt Al 2O 3 28 2wt MgO mag nesia rich and alumina rich magnesium aluminate spinel materials exist
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Magnesia Spinel Blends A combination of four articles will go over magnesium the element and the production of magnesia refractory products This is Part 4 Magnesia with Various Spinels Part 1 Magnesium the Element Part 2 Subtle role of Calcium in Magnesia Refractories Part 3 Magnesium Oxide refractories
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IMPORTANCE OF MAGNESIUM ALUMINATE SPINEL Mag Al spinel is used for refractory as well as structural applications at elevated temperatures due to its high melting point excellent mechanical strength and impressive chemical resistance It is the most Stable compound present in the MgO Al 2 O 3 system It is chemically compatible
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Effect of different raw materials on the solid state spinel formation and densification of magnesium aluminate spinel is studied Two different grades of commercially available alumina were used with fused sintered and chemical grades of magnesia to study spinel formation through phase analysis and densification behavior at different temperatures between 1200 °C and 1600 °C
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Magnesium Aluminate Spinels Magnesium aluminate spinel has excellent refractory properties with a melting point of sot ichiometric spinel of 2135° C All spinels have the ability to substitute large percentages of one or both of the cationic site components Al3 or Mg2 with other elements with the same charge and similar atom size
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Refractories as liners play an important role in the metallurgical glassmaking steel and ceramic industries Spinel based magnesium aluminate is an excellent refractory oxide for the production of high temperature materials focusing on emerging science and technology It offers the attractive combination of physical and chemical properties like high mechanical strength at elevated
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Magnesium aluminate spinel is a highly refractory material with a melting point of 2135oC Table 1 shows a comparison of the density thermal expansion coefficient and thermal conductivity of the end members MgO Al2O3 compared to the spinel phase The differences between these phases in thermal expansion are responsible in part for
Get PriceReaction sintered magnesia rich magnesium aluminate spinel
But as the hazardous character of chrome bearing materials is exposed work and use of magnesium aluminate gain momentum The major application areas of spinel refractories are transition and burning zones of cement rotary kilns side walls and bottom of steel teeming ladles and checker work of glass tank furnace regenerators
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A magnesium aluminate spinel bonded refractory can be formed which does not exhibit undue expansion due to the reaction of magnesia and alumina to form magnesium aluminate spinel between the raw compacted state and the fired ceramically bonded state when fired to a temperature of 1400° C if a very finely divided alumina with dense particles is used
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Synthesis of magnesium aluminate spinel MgAl2O4 was investigated by employing ball milling and co precipitation methods The starting materials aluminum hydroxides were obtained from the purified sodium hydroxide leaching solution of black dross The characteristics of the synthesized spinel was analyzed through X ray diffraction XRD scanning electron microscopy SEM images
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for refractory applications for example in the steel in dustry because of its suitable high temperature proper ties such as high strength at elevated temperatures and high resistance to basic slags 1 2 Besides the stoichiomet riccomposition 71 8wt Al 2O 3 28 2wt MgO mag nesia rich and alumina rich magnesium aluminate spinel materials exist
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Sarkar R Refractory applications of magnesium aluminate spinel Interceram Refractories Manual 2010 11–14 3 Racher P R McConnell R W Buhr A Magnesium aluminate spinel raw materials for high performance refractories for steel ladles
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These combined factors have led to a resurgence in interest in magnesium aluminate spinel raw materials Magnesium aluminate spinels have been used in steel making refractories for many years in a variety of different forms This paper reviews the production properties and performance of spinels Recent developments in the applications of
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However as hazar nesia–spinel bricks with 40 wt spinel containing dous character of chrome bearing materials is exposed 4 magnesia–magnesium aluminate co clinker resulted in the use of magnesium aluminate as an alternative phase best combination of properties
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Aluminate cement often refers to cement with calcium aluminate as the main component Calcium aluminate cement is a basic binder for unshaped refractories especially castable refractories It also has another name called high alumina cement Its chemical composition is mainly Al2O3 and CaO and some also contain quite a lot of Fe2O3 and SIO2
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The major application areas of magnesium aluminate spinel as refractory materials are transition and burning zones of cement rotary kiln bottom and side walls of steel teeming ladles chequer work of glass tank furnace regenerators
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