Rheology Of High Performance Alumina And Spinel
Preparation of Light Weight Alumina Spinel Refractory by
In order to reduce energy costs light weight alumina spinel refractories with tri modal pores were prepared by foaming process The influence of foaming agent and magnesia on the properties of light weight alumina spinel refractory was investigated The rheology of the original slurry and the density mechanical properties and microstructure of samples were evaluated
Get PriceCorundum Spinel CastableRongsheng Refractory
After the high temperature treatment or application the corundum spinel castables form three kinds of high melting mineral phases namely calcium hexaluminate magnesium aluminum spinel and brown corundum which form a good combination with each other and have good performance Corundum spinel castable refractory known as the optimal matrix
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A previous work Rodrigues Neto and Moreno 2007 reported the optimisation of the rheology of 40 vol suspensions of the same composition of that used in this work as a function of the nature and concentration of deflocculant the final pH the size ratio of alumina in the mixture and the mixing procedure However since the objective was to
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hollow alumina spheres an intermediate thermally grown oxide and a bottom aluminized bond coat The coating system is shown to display very low thermal conductivity and remarkable oxida tion resistance at high temperatures Keywords Slurry Viscosity Wetting Thermal Barrier Coating Thermal Conductivity Oxidation 1 Introduction
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Alumina magnesia and alumina spinel castables are widely used in steel ladle linings below the slag line the pocket block of purging plugs and injection metallurgy Calcium aluminate cement reacts with alumina and generates calcium hexaluminate CA 6 at high temperatures and it has been reported that this can improve the thermal behavior of castables 6 7
Get PriceRheology of High Performance Alumina and Spinel
Rheology of High Performance Alumina and Spinel Castables M Schnabel A Buhr J Dutton Marion Schnabel Andreas Buhr Jerry Dutton Almatis 60528 Frankfurt Germany Corresponding author M Schnabel E mail Marion Schnabel almatis Keywords alumina and spinel castables workability rheology Fig 1 Flow behaviours of suspensions 1
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Refractories as liners play an important role in the metallurgical glassmaking steel and ceramic industries Spinel based magnesium aluminate is an excellent refractory oxide for the production of high temperature materials focusing on emerging science and technology It offers the attractive combination of physical and chemical properties like high mechanical strength at elevated
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Insights into the rheology of alumina–silica containing castables were speculated through exploring submicron and nano sized particles The rheology of refractory concrete can be adapted properly according to the application manner and the specified requirements Rheologie of high performance alumina and spinel castables Novye Ogneupory
Get PriceAlmatis Calcined Aluminas
Calcined aluminas are alpha aluminas that consist primarily of sintered agglomerates of individual alumina crystals The size of these primary crystals depends upon the degree of calcination and the agglomerate size on the subsequent grinding steps The majority of calcined aluminas are supplied ground <63μm or fine ground <45μm
Get PriceSintering Performance of MgAl2O4 Spinel with Various
Magnesium aluminate spinel specimens with various Al2O3 content were prepared Sintering performance and microstructure of different kinds of MgAl2O4 spinel were studied It is found that the sintering of materials becomes more difficult with the increase in their Al2O3 contents Corundum begins to precipitate from the magnesium aluminate spinel with 85wt Al2O3 at 1400
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High processing cost of dense MAS ceramics is in the main responsible for its limited usage in certain important applications despite its excellent performance in them The volume expansion ∼8 associated with MAS phase formation from alumina and magnesia does not allow obtaining dense MAS bodies in a single stage reaction sintering process
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Ko Yung chao 6 found that the bond linkage between the CA 6 and spinel grains in the bonding matrix of alumina spinel castables is responsible for the increased hot modulus of rupture with both increased CaO content and temperature from 1300 ºC to 1500 ºC The results show that porosity decreased with increasing microsilica addition
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Reactive aluminas are specially designed for the production of high performance refractories where defined particle packing rheology and consistent placement characteristics are as important as the superior physical properties of the final product Reactive aluminas are fully ground down to the primary single crystals by highly efficient
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High Purity Alumina HPA is chemically inert in most environments has a very high melting point has a very low electrical conductivity is a good conductor of heat and is very abrasive HPA adds significant performance and safety characteristics when used in lithium battery separators
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At low humidity levels the electrical resistivities of alumina and spinel coatings were comparable on order of magnitude of 10 11 Ω m A dramatic decrease in resistivity of about five orders of magnitude for alumina coatings and about four orders of magnitude for spinel coatings at a very high humidity 95 RH was observed
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nel grains that protect the spinel grains against AR 78 and AR 90 is therefore recommended further corrosion Volume stability Established practice sets a total spinel content of 15 30 for alumina refractories in contact with steel slag High quality pre reacted spinels ensure volume stability during firing and are therefore less
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Corundum Spinel Castable for Arc Furnace Definition the corundum spinel castables form three kinds of high melting mineral phases namely calcium hexaluminate magnesium aluminum spinel and brown corundum after the high temperature treatment or application which form a good combination with each other and have good performance
Get PricePREPARATION AND GRAIN GROWTH OF MAGNESIA
For example when alumina fibers were prepared by adding MgO in the fibers the MgO reduced the fibers grain size and increased its tensile strength 8 MgO was a kind of cheap and common sintering aid to improvement ceramic density for fabricated Magne sia alumina spinel MgAl 2 O 4 MAS will be obtained by adding MgO in alumina
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High alumina castable with presynthesized and in situ spinel formation is studied using two different lime containing high alumina cements Vibratable castable compositions were studied by conventional processing using a distribution coefficient of 0 29 and heat treatments at 110 900 and 1500°C Slightly lower density and strength values were found for in situ spinel forming compositions
Get PriceSpinel containing alumina based refractory castables
Due to their high corrosion resistance to basic slags either pre formed or in situ spinel MgAl 2 O 4 containing refractory castables are nowadays widely used as steel ladle linings Nevertheless whereas the pre formed spinel castables present high volumetric stability and a well known processing technology the in situ spinel castables still require further understanding due to the
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High alumina cement Al 2 O 3 = 74 2 and preformed alumina rich spinel Al 2 O 3 = 90 02 were the other important microconstituents The preformed magnesium aluminate spinel helps to form more calcium hexa aluminate phases in the castable at elevated temperature due to its association with extra corundum phases aside from spinel
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alteo alumina 2018 HIGH PERFORMANCE REFRACTORIES SPECIAlTy AluMINAS FOR Calcined aluminas Reactive aluminas modal AC34 AC44 from AC34B3 to AC34B6 GA4R AR12B5 PFR P172SB PFR20 P122B PBRP FR40 M4R Bricks Others High alumina bricks Gunning mixes Ceramic fi bers Sliding plates Electrofused bricks Rheology Setting time Shaping
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This aspect is attributed to their high surface areas and also to their impact on the castable rheology After casting all the castables were cured at 501C for 24 h in a humid environment dried at 1101C for 24 h and calcined at 6001C for 5 h heating rate 5 11C/min TAo200 mm as the weight content of alumina required to form spinel is 2
Get PriceSintering Performance of MgAl2O4 Spinel with Various
Magnesium aluminate spinel specimens with various Al2O3 content were prepared Sintering performance and microstructure of different kinds of MgAl2O4 spinel were studied It is found that the sintering of materials becomes more difficult with the increase in their Al2O3 contents Corundum begins to precipitate from the magnesium aluminate spinel with 85wt Al2O3 at 1400
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Fig 1 shows the flow curves of the as prepared slip and after ball milling for 15 30 and 45 min without pH readjustment The unmilled slip was nearly Newtonian at low shear rate but at high shear rates it shows a small thixotropic loop When milling for 15 min the viscosity η largely increases and the slip becomes shear thickening This makes the viscosity to increase faster and the
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a potential route to improve the performance of the final product For this purpose many types of inorganic or metallic fillers with high thermal conductivity low thermal expansion coefficient and low electrical conductivity such as silica 5–10 alumina Al2O3 11–14 aluminum nitride
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Refractories as liners play an important role in the metallurgical glassmaking steel and ceramic industries Spinel based magnesium aluminate is an excellent refractory oxide for the production of high temperature materials focusing on emerging science and technology It offers the attractive combination of physical and chemical properties like high mechanical strength at elevated
Get PriceThe impact of pre formed and in situ spinel formation on
Alumina–magnesia and alumina–spinel castables present some unique characteristics Whereas the in situ spinel MgAl 2 O 4 formation provides an enhanced corrosion and thermal shock resistance to the castable the composition with pre formed grains shows higher volumetric stability and do not have the inherent MgO hydration problems As these distinct ways of spinel incorporation result
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A ceramic copper alumina silica catalyst CAS C for dehydrogenation of cyclohexanol to cyclohexanone in the process of carbamide production was used to study the rheological and mechanical properties of the copper containing alumina silica plastic material depending on its composition The provided data characterize the effect of the process and design conditions of molding the material in a
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thermal treatment high temperature and corrosion by slag and smoke respectively The alumina spinel castables show good properties such as high modulus of rupture low porosity high density good resistance to thermal sock high refractoriness and good resistance to slag penetration and corrosion Another most important factor of castables is
Get PriceEffect of mechanical activation on the rheology and
A previous work Rodrigues Neto and Moreno 2007 reported the optimisation of the rheology of 40 vol suspensions of the same composition of that used in this work as a function of the nature and concentration of deflocculant the final pH the size ratio of alumina in the mixture and the mixing procedure However since the objective was to produce porous bodies coarse raw materials without
Get PricePreparation of Light Weight Alumina Spinel Refractory by
The results showed that light weight alumina spinel refractory contained a highly interconnected network of spherical cells consisting of the large sized cells larger than 40 um moderate sized pores averaging about 20 um and small sized voids which mainly attributed to the foaming agent and in situ formation of spinel
Get PriceRheology of refractory concrete An article review
Reactive alumina is fine alumina powders with small primary crystal size <1 μm high specific surface area between 5 and 11 m 2 /g specific gravity SG approx 3 95 g/cm 3 and low soda levels <0 15 Its particle size distribution follows multi modal character which reduces the dilatant character but its plate like morphology makes interlocking structure which makes paste layers stiff to move
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