Petroleum Coke Hazards
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Petroleum Coke as its name implies is a derivative of the petroleum industry In its carriage requirements and industrial usages it is however akin to coals Raw petroleum coke petcoke for short is a black solid residue from the petroleum refining process It is liable to heat and to spontaneously combust so similar precautions should be
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Incompatibilities This Graphite/Petroleum coke mixture is incompatible with all oxidizing agents Dust Explosibility Hazards Very finely divided graphite powder poses a very slight risk of dust explosion hazard Dust class ST1 MIE greater that 10 J very low hazard of spark ignition The Portland cement fraction of this mixture
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While not specific to Petroleum Coke long term inhalation of dusts may cause particle burden lung overload and fibrosis 3 Composition/information on ingredients
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Petroleum Loading and Unloading Procedures Basic Safety Basic Safety 1 No persons other than authorized personnel are allowed in the loading area 2 No smoking or open flames are permitted in the loading area 3 No one is permitted in the cab of a truck while loading 4 No mechanical repair work service checks or cleaning
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Petroleum Coke 100 Notes The manufacturer has voluntarily elected to reflect exposure limits contained in OSHA s 1989 air contaminants standard in its MSDS s even though certain of those exposure limits were vacated in 1992 3 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW PETROLEUM COKE IS A CHUNKY POROUS BLACK CARBON MATERIAL
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PETROLEUM COKE Page 3 of 6 Effective Date 12/15/13 This material contains fused polycyclic hydrocarbons The OSHA interpretation of coal tar pitch volatiles Section 1910 1002 is as follows Coal tar pitch volatiles include the fused polycyclic hydrocarbons which volatize from the
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Synonyms Thermocracked Petroleum Coke Petroleum Coke Anode Grade Petroleum Coke Fluid Grade and Petroleum Coke Fuel Grade See section 16 for complete information Physical hazards Not classified Health hazards Not classified OSHA defined hazards Combustible dust Label elements Hazard symbol None
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Petroleum coke was found to be non carcinogenic in mice in chronic skin painting studies with coke dust Petroleum coke was found not to be carcinogenic in monkeys and rats in a two year inhalation study at concentrations up to 30 mg/m 3
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Other adverse effects Like any solid petroleum coke could interfere with aquatic life by physical effects such as clogging gills or burying of sediment dwellings organisms if released in very large quantities and if the density was
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SECTION 2 Hazards identification Other hazards which do not result in classification Handling and/or processing of this material may generate a dust which can cause mechanical irritation of the eyes skin nose and throat Containers to be fitted with child resistant fastenings Not applicable Tactile warning of dangerNot applicable
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Petcoke is short for petroleum coke which is a byproduct of the oil refinery coking process that produces low cost fuel often with a high sulphur content Petcoke may also be known as green delayed coke sponge coke needle coke delayed coke or raw coke fuel grade Hold cleanliness Clean and dry as relevant to the hazards of the cargo
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While there are many hazards associated with green coke in the unit the toxicity and environmental impacts of the petroleum coke itself seems relatively low A report published by the EPA link here in 2007 entitled Petroleum Coke Category Analysis and Hazard Characterization demonstrated no or low levels of toxicity in the following categories
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Chemical Name Calcined Petroleum Coke Percent 70 80 CAS Number Chemical Name Coal Tar Pitch Percent 20 30 CAS Number HAZARDS IDENTIFICATIONSECTION 3 EMERGENCY OVERVIEW HAZARDS PRESENT TO MAN AND THE ENVIRONMENT Coal Tar Pitch is a CARCINOGEN HANDLE WITH EXTREME CAUTION Coal Tar Pitch Can irritate
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These substances are coke petroleum and coke petroleum calcined also referred to as green coke and calcined coke respectively Green coke is a UVCB substance that is formed during the process of refining crude oil and oil sands upgrading Further heating of green coke at high temperatures produces the substance calcined coke
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Unusual Fire and Explosion Hazards In dust form this material is combustible at high temperatures Dusts may form explosive mixtures in air Material itself burns with difficulty ACCIDENTAL RELEASE MEASURESSECTION 6
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Calcined Petroleum Coke Grade 218L Product Description Calcined Petroleum Coke Manufacturer Asbury Carbons PO Box 144 405 Old Main Street Asbury NJ 08802 Emergency Phone Information Phone Fax Date Prepared February 15 2010 Preparer optional AVT Section 2Hazards Information
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petroleum coke or petcoke Petcoke is a co product of several processes used during petroleum refining to upgrade residuum into gasoline and middle distillate range fuels Residuum or resid is the substance that remains after refineries initially distill heavy crude oils Nearly half of
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According to the MSDS petroleum coke is considered hazardous under 29 CFR 1910 1200 Hazard Communication For a more in depth analysis see below The following is a quote from the Petroleum Coke
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Thermal hazards Wear appropriate thermal protective clothing when necessary Green Petroleum Coke SDS US 937957 Version # 02 Revision date 08 January 2018 Issue date 19 May 2017 2
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Coke petroleum Coke petroleum calcined Structural Formula See Appendix Summary CASRN is a grayish black carbonaceous solid that is obtained from the heaviest portions of crude oil CASRN is a product derived from CASRN under reducing conditions in kilns or hearths heated to over 1 200°C
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Petroleum Coke Category SPONSORED CHEMICALS Petroleum coke green CASRN Petroleum coke calcined CASRN hazards toxicity for humans or the environment The Environmental Protection Agency s Office of Pollution Prevention and Toxics OPPT is
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Figure 3 Effects of petroleum coke size on the zinc removal left and metallization degrees right MW power 1 1kW processing time 15min coke addition 15 wt The original dusts have most particles smaller than 2 µm As the coke particle size went smaller the surface areas for chemical reactions became larger
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LORESCO TYPE SC 3 421 J M Tatum Ind Pk Drive Revised 1/6/2011 Hattiesburg MS 39401 Page 1 of 3 SECTION IMATERIAL IDENTIFICATION 24 HOUR EMERGENCY INFORMATION PRODUCT/CHEMICAL NAME Calcined Fluid Petroleum Coke Loresco Inc 601 IDENTIFICATION No SC 3 CHEMTREC 800 CHEMICAL FAMILY HMIS/NEPA
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Product Name PETROLEUM COKE Revision Date 26 Feb 2015 Page 4 of 9 temperatures Do not store in open or unlabelled containers SECTION 8 EXPOSURE CONTROLS PERSONAL PROTECTION Substance Name Form Limit/Standard Note Source COKE PETROLEUM as V2O5 TWA 0 05 mg/m3 Supplier COKE PETROLEUM Respirable fraction
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Petroleum coke delayed process and fluid process was found not to be mutagenic in a rat in vivo bone marrow cytogenetic test a mouse lymphoma assay and an Ames mutagenicity assay Reactivity The product is non reactive under normal conditions SDS ID NO 0109MAR019Product name Marathon Petroleum Petroleum Coke Page 5 of 9
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Conclusion/Summary Based on CONCAWE assessment of petroleum coke Not considered to be toxic to the reproductive system Irritation/Corrosion Not available Conclusion/Summary Skin Based on CONCAWE assessment of petroleum coke Non irritating to the skin Eyes Based on CONCAWE assessment of petroleum coke Non irritating to the eyes Sensitization
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5 b Specific Hazards arising from the chemical When burned toxic smoke and vapor may be emitted including oxides of carbon metal oxides and other toxic vapors Coke dust may form combustible mixtures in the air
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SAFETY DATA SHEET 1 Identification Product identifier Petroleum Coke Uncalcined Other means of identification Product code KOMSA2000CAEN CAS number Synonyms Pet coke Green Coke Delayed Coke Sponge Coke Thermocracked Coke Recommended use Fuel Only for professional use
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Chemical Name Calcined Petroleum Coke Percent 70 80 CAS Number Chemical Name Coal Tar Pitch Percent 20 30 CAS Number HAZARDS IDENTIFICATIONSECTION 3 EMERGENCY OVERVIEW HAZARDS PRESENT TO MAN AND THE ENVIRONMENT Coal Tar Pitch is a CARCINOGEN HANDLE WITH EXTREME CAUTION Coal Tar Pitch Can irritate
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A potentially catastrophic hazard which must be controlled in coke handling operations is the possibility of a combustible dust explosion or deflagration Petroleum coke is readily able to form dust clouds of finely divided combustible material
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Other means of Calcinated coke Petroleum Calcined Coke Calcinable anodegrade coke identification 1 1 Product identifier 1 3 Details of the supplier of the safety data sheet 5 2 Special hazards arising from the substance or mixture 5 3 Advice for firefighters
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Coke petroleum A solid material resulting from high temperature treatment of petroleum fractions It consists of carbonaceous material and contains some hydrocarbons having a high carbon to hydrogen ratio Regulatory process names 2 IUPAC names 3 Other identifiers 2 Print infocard
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